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Manwha Ch. 29 already introduced Catherine and Edith to each other. In the novel, they met around episode 85 (still a lot of stories to cover before they actually meet) and Killian was with Edith to protect her from Catherine’s verbal attack. It was a ball where all noble families gathered including the Rudwicks, Sinclair and Rigolhoffs. And Instead of Cliff, it was Reeze who told Catherine about the poison incident. Killian argued with Reeze in front of everyone as to why she had to tell the poison story when she herself “wished” for the story to be buried and forgotten. In the end of the scene, Killian did a good job defending Edith and they went home to have some sexy time lol if u kno what i mean.