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If you're talking about this series, the couple appears in chapter 80. If you mean Robber x Lover, sorry to say, they are a side couple and their relationship kind of develops over time of the comic (as far as I remember at least, it's been a good few years since i last read it and I forgot to catch up after MC's old school friend (orange hair) had just appeared.) ( ̄∇ ̄")
that couple was in the robber lover argghh they're married nowwww